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Article
Publication date: 17 April 2023

Uchenna Luvia Ezeamaku, Innocent Eze, Nkiru Odimegwu, Angela Nwakaudu, Amarachukwu Okafor, Okechukwu Dominic Onukwuli and Ikechukwu Abuchi Nnanwube

The purpose of this study is to investigate starch mucor (SM) in potassium iodide (KI) as corrosion inhibitor of aluminium in hydrochloric acid (HCl) medium.

Abstract

Purpose

The purpose of this study is to investigate starch mucor (SM) in potassium iodide (KI) as corrosion inhibitor of aluminium in hydrochloric acid (HCl) medium.

Design/methodology/approach

The SM in KI was characterized by gravimetric, scanning electron microscopy, electrochemical impedance spectroscopy measurements, potentiodynamic polarization and gas chromatography-mass spectrometer techniques. The inhibition efficiency was optimized using response surface methodology.

Findings

The result revealed that the inhibitor inhibited corrosion at a low concentration with the rate of inhibition increasing as the concentration of the inhibitor increased. The inhibition efficiency increases as the temperature was increased with slight incorporation of the inhibitor (SM in KI). This indicates that the corrosion control is both inhibitor (SM in KI) and temperature dependent.

Originality/value

The research results can provide the basis for using SM in KI as corrosion inhibitor of aluminium in HCL medium. Mixed-type inhibitor nature of SM was proved by cathodic and anodic nature of the polarization curves.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Open Access
Article
Publication date: 16 December 2022

Uchenna Luvia Ezeamaku, Chinyere Ezekannagha, Ochiagha I. Eze, Nkiru Odimegwu, Angela Nwakaudu, Amarachukwu Okafor, Innocent Ekuma and Okechukwu Dominic Onukwuli

The impact of potassium permanganate (KMnO4) treatment on the tensile strength of an alkali-treated pineapple leaf fiber (PALF) reinforced with tapioca-based bio resin (cassava…

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Abstract

Purpose

The impact of potassium permanganate (KMnO4) treatment on the tensile strength of an alkali-treated pineapple leaf fiber (PALF) reinforced with tapioca-based bio resin (cassava starch) was studied.

Design/methodology/approach

The PALF was exposed to sodium hydroxide (NaOH) treatment in varying concentrations of 2.0, 3.7, 4.5 and 5.5g prior to the fiber treatment with KMnO4. The treated and untreated PALFs were reinforced with tapioca-based bio resin. Subsequently, they were subjected to Fourier transform infrared (FTIR) and tensile test analysis.

Findings

The FTIR analysis of untreated PALF revealed the presence of O-H stretch, N-H stretch, C=O stretch, C=O stretch and H-C-H bond. The tensile test result confirmed the highest tensile strength of 35N from fiber that was reinforced with 32.5g of cassava starch and treated with 1.1g of KMnO4. In comparison, the lowest tensile strength of 15N was recorded for fiber reinforced with 32.5g of cassava starch without KMnO4 treatment.

Originality/value

Based on the results, it could be deduced that despite the enhancement of bioresin (cassava starch) towards strength-impacting on the fibers, KMnO4 treatment on PALF is very vital for improved tensile strength of the fiber when compared to untreated fibers. Hence, KMnO4 treatment on alkali-treated natural fibers preceding reinforcement is imperative for bio-based fibers.

Details

Arab Gulf Journal of Scientific Research, vol. 41 no. 3
Type: Research Article
ISSN: 1985-9899

Keywords

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